Conformational control over an aldehyde fragment by selective vibrational excitation of interchangeable remote antennas
CHEMICAL COMMUNICATIONS, vol.54, no.38, pp.4778-4781, 2018 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 54 Issue: 38
- Publication Date: 2018
- Doi Number: 10.1039/c8cc01052h
- Journal Name: CHEMICAL COMMUNICATIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.4778-4781
- Istanbul Kültür University Affiliated: Yes
Abstract
We apply interchangeable vibrational antennas (OH or NH2 group) to achieve unprecedented conformational control over the heavy aldehyde fragment in 2-formyl-2H-azirine. The two aldehyde conformers were manipulated bi-directionally, using selective vibrational excitation with narrowband near-infrared (NIR) light tuned at the wavenumbers corresponding to OH and NH2 stretching overtones and combination modes.