Conformational control over an aldehyde fragment by selective vibrational excitation of interchangeable remote antennas
CHEMICAL COMMUNICATIONS, cilt.54, sa.38, ss.4778-4781, 2018 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 54 Sayı: 38
- Basım Tarihi: 2018
- Doi Numarası: 10.1039/c8cc01052h
- Dergi Adı: CHEMICAL COMMUNICATIONS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.4778-4781
- İstanbul Kültür Üniversitesi Adresli: Evet
Özet
We apply interchangeable vibrational antennas (OH or NH2 group) to achieve unprecedented conformational control over the heavy aldehyde fragment in 2-formyl-2H-azirine. The two aldehyde conformers were manipulated bi-directionally, using selective vibrational excitation with narrowband near-infrared (NIR) light tuned at the wavenumbers corresponding to OH and NH2 stretching overtones and combination modes.