The FT-IR spectra of pyrazinamide complexes of transition metal(II) tetracyanonickelate

AKYÜZ S.

JOURNAL OF MOLECULAR STRUCTURE, vol.651, pp.541-545, 2003 (SCI-Expanded, Scopus) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 651
  • Publication Date: 2003
  • Doi Number: 10.1016/s0022-2860(02)00675-0
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.541-545
  • Istanbul Kültür University Affiliated: No

Abstract

M(PZA)(2)Ni(CN)(4) (where M = Mn, Co,Fe, Ni or Cd; PZA = pyrazinamide} complexes have been prepared for the first time and their FT-IR spectra are reported in the 400-4000 cm(-1) region. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni(CN)(4)(-2) ions bridged by M(PZA)(2)(+2) cations. PZA is coordinated to M(II) through the oxygen atom of the carbonyl group. (C) 2002 Elsevier Science B.V. All rights reserved.