The FT-IR spectra of pyrazinamide complexes of transition metal(II) tetracyanonickelate
JOURNAL OF MOLECULAR STRUCTURE, cilt.651, ss.541-545, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 651
- Basım Tarihi: 2003
- Doi Numarası: 10.1016/s0022-2860(02)00675-0
- Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.541-545
- İstanbul Kültür Üniversitesi Adresli: Hayır
Özet
M(PZA)(2)Ni(CN)(4) (where M = Mn, Co,Fe, Ni or Cd; PZA = pyrazinamide} complexes have been prepared for the first time and their FT-IR spectra are reported in the 400-4000 cm(-1) region. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni(CN)(4)(-2) ions bridged by M(PZA)(2)(+2) cations. PZA is coordinated to M(II) through the oxygen atom of the carbonyl group. (C) 2002 Elsevier Science B.V. All rights reserved.