A new Schiff base ligand as a fluorescence probe for Cu(II) detection in semi-aqueous solution: synthesis, characterization, fluorescence and mechanistic insight
INORGANICA CHIMICA ACTA, cilt.528, 2021 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 528
- Basım Tarihi: 2021
- Doi Numarası: 10.1016/j.ica.2021.120623
- Dergi Adı: INORGANICA CHIMICA ACTA
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core
- İstanbul Kültür Üniversitesi Adresli: Hayır
Özet
A new Schiff base fluorescence probe for Cu2+ was designed and synthesized by reaction between 2-[(3-formylphenoxy)2-hydroxypropoxy]benzaldehyde and 4-aminophenol. The probe was characterized by elemental analysis, FTIR, H-1- and C-13 NMR, and fluorescence spectroscopies. DFT calculations were carried out to further characterize the structure of the compound in solution, by carrying out an in-depth conformational study. The obtained results showed fluorescence quenching of the fluorophore when Cu2+ binds to the ligand (L) in semiaqueous solution (DMF:H2O 1:1) and revealed that the probe has high selectivity for Cu2+ compared to the other metal ions analyzed (Ag+, Co2+, Mg2+, Ni2+, Pb2+, Zn2+, Cd2+, Cr3+, Hg2+, Na+, Ba2+, Mn2+ and Fe3+). The stoichiometry of the complex formed between Cu2+ and L has been determined from a Job's plot as being 1:1 and a structure for the complex Cu2+/L is proposed. The mechanism for the quenching of the fluorescence in the presence of Cu2+ was evaluated on the basis of time-dependent DFT (TD-DFT) results.